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The molecule of the dinuclear title compound, [Tl(2)(C(9)H(10)NS(2))(6)], possesses a crystallographically imposed centre of symmetry. Each Tl(III) atom is seven-coordinated by S atoms of four different dithio-carbamate anions in a distorted penta-gonal-bipyramidal coordination geometry. The crystal structure is stabilized by a C-H⋯S hydrogen-bond inter-action linking complex mol-ecules into chains running parallel to the b axis. Intramolecular C-H⋯S hydrogen bonds are also present.

acta crystallographica. section e

Bis(μ-N-benzyl-N-methyldithiocarbamato)-1:2κ3S,S′:S′;1:2κ3S:S,S′-bis[bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)thallium(III)]