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In the title chain compound, [Ag(NO 3 )(C 26 H 24 P 2 )]  n  , the bis­(diphenyl­phosphino)ethane (dppe) units link the Ag +  ions into chains along [001]. A nitrate anion is coordinated to the Ag atom. There is a centre of symmetry at the mid-point of the ethane C—C bond and a twofold rotation axis passes through the Ag, N and terminal O atoms. Each Ag atom is four-coordinated in a distorted tetra­hedral geometry by two O atoms of the nitrate anion and two P atoms of dppe ligands. The two aromatic rings are oriented at a dihedral angle of 73.77 (3)°.

catena-Poly[[(nitrato-κ2O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ2P:P′]

catena-Poly[[(nitrato-κ²O,O′)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ²P:P′]