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In the title compound, [Cu(C 8 F 4 O 4 )(C 5 H 5 N) 3 ]  n  , the Cu II  atom, lying on a twofold rotation axis, is five-coordinated by two O atoms from two tetra­fluoro­terephthalate ligands and three N atoms from three pyridine ligands in a distorted trigonal-bipyramidal geometry. Adjacent Cu II  atoms are connected  via  the bridging tetra­fluoro­terephthalate ligands into a one-dimensional chain running along the [101] direction.

catena-Poly[[tris(pyridine-κN)copper(II)]-μ-tetrafluoroterephthalato-κ2O1:O4]

catena-Poly[[tris(pyridine-κN)copper(II)]-μ-tetrafluoroterephthalato-κ²O¹:O⁴]