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In the title compound, [Ni(C 5 H 7 O 2 ) 2 (C 12 H 16 N 3 O 2 )], the Ni II  cation is hexa­coordinated by four O and two N atoms, showing a slightly distorted octa­hedral geometry. The Ni II  cation lies on an inversion centre, as a consequence of which the asymmetric unit comprises one half-mol­ecule. The four O atoms belonging to two pentane-2,4-dionate ligands lie in the equatorial plane and two pyridyl N atoms occupy the axial coordination sites.

Bis(pentane-2,4-dionato)bis[2-(4-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl 3-oxide]nickel(II)