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The title compound, C 14 H 10 Br 2 O, is a biphenyl derivative containing a –CH 2 —O—CH 2 – bridge in the 2,2′-position. The compound displays a twisted conformation with the two benzene rings making a dihedral angle of 45.02 (5)°, while the central seven-membered ring is in a boat conformation. The mol­ecule lies on a crystallographic twofold axis of symmetry passing through the O atom and bis­ecting the 1,1′ C—C bond.

3,9-Dibromo-5,7-dihydrodibenzo[c,e]oxepine