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The title iron(III) compound, [Fe(C 12 H 21 N 2 Si) 2 Cl], is monomeric. The Fe atom is  N , N ′-chelated by the  N -silylated anilide ligand. The two ligands around the Fe atom are arranged  trans  to each other. The Fe—N amino  bond is longer than the Fe—N anilide  bond by about 0.37 Å. The mol­ecule displays a pseudo-twofold rotation. The five–coordinate Fe atom demonstrates a highly distorted trigonal–bipyramidal geometry.

Chloridobis{N-[(dimethylamino)dimethylsilyl]-2,6-dimethylanilido-κ2N,N′}iron(III)

Chloridobis{N-[(dimethylamino)dimethylsilyl]-2,6-dimethylanilido-κ²N,N′}iron(III)