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The polymeric title compound, {[Ni(C 8 H 18 O 2 PS 2 ) 2 (C 12 H 10 N 4 )]·2C 7 H 7 }  n  , has a linear topology and features octa­hedrally coordinated Ni atoms with a  trans -N 2 S 4  donor set. The toluene solvent mol­ecules occupy channels defined by the three-dimensional stacking of the polymeric chains. The Ni atom is located at a centre of inversion and the bridging 1,2-bis­(4-pyridylmethyl­ene)hydrazine4-pyridine mol­ecule is also disposed about a centre of inversion. One isobutoxy group is disordered equally over two positions.

acta crystallographica. section e

catena-Poly[[[bis(O,O′-diisobutyl dithiophosphato-κ2S,S′)nickel(II)]-μ-1,2-bis(4-pyridylmethylene)hydrazine-κ2N:N′] toluene disolvate]