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There are two formula units in the asymmetric unit of the title compound, C 21 H 17 N 5 ·1.5H 2 O. The imidazo[4,5- f ][1,10]phen­an­throline unit is almost coplanar with the benzene ring, the dihedral angles between them being 8.91 (5) and 4.93 (6)° in the two mol­ecules. The crystal structure is stabilized by a series of hydrogen bonds between the water mol­ecules and the N atoms of the imidazophenanthroline groups.

2-[4-(Dimethylamino)phenyl]imidazo[4,5-f][1,10]phenanthroline sesquihydrate