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In the crystal structure of the title compound, (C 10 H 15 ClN 2 )[ZnCl 4 ]·H 2 O, the Zn atom is coordinated by four Cl atoms in a tetrahedral geometry. The water mol­ecules and the 1-(4-chloro­phen­yl)piperazine-1,4-diium cations inter­act with the [ZnCl 4 ] 2−  anions through O—H⋯Cl, N—H⋯Cl, N—H⋯O and C—H⋯Cl hydrogen bonds (five simple and one bifurcated). Inter­molecular π–π stacking inter­actions are present between adjacent aromatic rings of 1-(4-chloro­phenyl)­piperazine-1,4-diium cations (the centroid–centroid distance is 3.453 Å).

1-(4-Chlorophenyl)piperazine-1,4-diium tetrachloridozincate(II) monohydrate