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The asymmetric unit of the title compound, (C(12)H(28)N(2)O(4))[AuCl(4)](2)·2H(2)O, contains one half-cation, one anion and one water mol-ecule; the cation is centrosymmetric. The Au ion has a square-planar coordination. In the crystal structure, intra-molecular N-H⋯O and O-H⋯O, and inter-molecular N-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds link the ions and water mol-ecules, forming a supra-molecular structure.

1,4,10,13-Tetraoxa-7,16-diazoniacyclooctadecane bis[tetrachloridoaurate(III)] dihydrate