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The title compound, [Fe 2 (C 5 H 5 ) 2 (C 24 H 22 BP 2 )(CO) 4 ][FeCl 4 ]·CHCl 3 , is an oxidation product of CpFe(CO) 2 PPh 2 BH 3 . One pair of phenyl rings attached to the two different P atoms are almost parallel, as are the other pair [dihedral angles = 8.7 (5) and 8.9 (5)°]. The planes of the two cyclo­penta­dienyl rings are inclined by 26.8 (7)° with respect to each other. The carbonyl groups at each Fe atom are almost perpendicular [C—Fe—C = 92.6 (6) and 94.3 (5)°].

acta crystallographica. section e

μ-Bis(diphenylphosphanyl)borato-κ2P:P′-bis[dicarbonyl(η5-cyclopentadienyl)iron(II)] tetrachloridoferrate(III) chloroform solvate