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In the title salt, [Ag(C 26 H 24 P 2 ) 2 ][Sn(C 2 ClF 2 O 2 ) 2 (C 6 H 5 ) 2 (C 6 H 4 Cl)], the Ag I  atom has a tetra­hedral and the Sn IV  atom a  trans -trigonal-bipyramidal coordination geometry. In the anion, the chloro substituent is disordered over two rings (occupancy ratio 0.81:0.19); the two chloro­difluoro­methyl groups are also disordered over two sites for their halogen atoms (occupancy ratios 0.72:0.28 and 0.70:0.30).

acta crystallographica. section e

Bis[1,2-bis(diphenylphosphino)ethane-κ2P:P′]silver(I) bis(chlorodifluoroacetato-κO)(4-chlorophenyl)diphenylstannate(IV)