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The title compound, [Na 4 (CH 2 O 6 S 2 ) 2 (H 2 O) 5 ]  n  , was crystallized from an aqueous solution. The sodium ions are surrounded and bridged by O atoms from coordinated water mol­ecules and sulfonate ions in a three-dimensional neutral network. The crystal structure is also stabilized by an intricate system of hydrogen bonds.

Poly[penta-μ-aqua-μ6-methylenedisulfonato-μ5-methylenedisulfonato-tetrasodium(I)]

Poly[penta-μ-aqua-μ₆-methylenedisulfonato-μ₅-methylenedisulfonato-tetrasodium(I)]