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The title compound, [Cu 2 {SC(NH 2 )NHNH 2 } 6 ]I 2 , was obtained by the reaction of CuI and thio­semicarbazide (TSCZ) in acetonitrile. Each Cu I  ion is coordinated by four S atoms of the TSCZ ligands, forming a tetra­hedral geometry. Centrosymmetric dimers are formed by two coordination tetra­hedra sharing a common edge, with a Cu⋯Cu distance of 2.8236 (14) Å. The I −  ion does not have any direct inter­action with the metal. The crystal structure is stabilized by weak N—H⋯N, N—H⋯S and N—H⋯I hydrogen bonds, forming a three-dimensional network structure.

Di-μ-thiosemicarbazide-κ4S:S-bis[bis(thiosemicarbazide-κS)copper(I)] diiodide

Di-μ-thiosemicarbazide-κ⁴S:S-bis[bis(thiosemicarbazide-κS)copper(I)] diiodide