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In the title compound, alternatively called xylazine hydro­chloride monohydrate, C 12 H 17 N 2 S + ·Cl − ·H 2 O, the six-membered thia­zine ring is in a half-chair conformation. In the crystal structure, six component centrosymmetric clusters are formed  via  inter­molecular O—H⋯Cl, N—H⋯O and N—H⋯Cl hydrogen bonds involving xylazine cations, chloride anions and water mol­ecules.

N-(2,6-Dimethylanilino)-5,6-dihydro-4H-1,3-thiazin-3-ium chloride monohydrate