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The title compound, [SnI 4 (C 25 H 22 O 2 P 2 )]·CHCl 3 , crystallized from a chloro­form solution of SnI 4  and the diphosphine CH 2 (PPh 2 ) 2  exposed to air. The monomeric complex displays a distorted octa­hedral coordinaton for the tin(IV) atom with average Sn—I and Sn—O bond lengths of 2.79 (2) and 2.15 (1) Å, respectively.

Tetraiodido[methylenebis(diphenylphosphine oxide)-κ2O:O′]tin(IV) chloroform solvate

Tetraiodido[methylenebis(diphenylphosphine oxide)-κ²O:O′]tin(IV) chloroform solvate