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The mol­ecule of the dinuclear title compound, [Sn 2 (C 5 H 9 ) 2 (C 6 H 5 ) 4 (C 2 F 3 O 2 ) 2 (C 28 H 28 O 2 P 2 )], lies on a center of inversion at the mid-point of the central C—C bond of the bridging phosphine oxide ligand. The Sn atom is five-coordinate in a  trans -C 3 SnO 2  trigonal-bipyramidal geometry.

[μ-1,4-Bis(diphenylphosphinoyl)butane-κ2O:O′]bis[cyclopentyldiphenyl(trifluoroacetato-κO)tin(IV)]

[μ-1,4-Bis(diphenylphosphinoyl)butane-κ²O:O′]bis[cyclopentyldiphenyl(trifluoroacetato-κO)tin(IV)]