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The asymmetric unit of the title complex, [Cu 2 (CN) 2 (C 20 H 16 N 6 S 2 )]  n  , contains one Cu I  cation, one cyanide ligand and half of a centrosymmetric 1,2-bis­[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]ethane (bppe) ligand. The Cu I  atom displays a trigonal coordination geometry, being surrounded by one C atom from one cyanide anion and two N atoms from one cyanide and one bppe ligand. In the complex, each cyanide anion links two Cu I  atoms in a bis-monodentate mode into a zigzag [–Cu—CN–]  n   chain. Two parallel chains are linked by bppe ligands into a ladder chain.

Poly[{μ2-1,2-bis[4-(3-pyridyl)pyrimidin-2-ylsulfanyl]ethane}di-μ2-cyanido-dicopper(I)]

Poly[{μ₂-1,2-bis[4-(3-pyridyl)pyrimidin-2-ylsulfanyl]ethane}di-μ₂-cyanido-dicopper(I)]