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In the title complex, {[Ag 2 (CF 3 O 3 S) 2 (C 30 H 20 N 6 )]·C 6 H 6 }  n  , the two independent Ag I  ions are each coordinated by two N atoms and one O atom in a ‘T-shaped’ geometry. In the crystal structure, 1,2-bis­[(3-cyano­benzyl­idene)hydrazono]-1,2-diphenyl­ethane ligands act as bridging ligands and each coordinates to four Ag I  ions, resulting in a one-dimensional chain structure. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds.

Poly[[{μ4-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}bis(trifluoromethanesulfonato)disilver(I)] benzene solvate]

Poly[[{μ₄-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}bis(trifluoromethanesulfonato)disilver(I)] benzene solvate]