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In the title compound, [Mn(3)(C(8)H(10)O(4))(3)(C(18)H(10)N(4))(2)], one Mn atom and one cyclohexane-1,4-dicarboxylate (chdc) ligand are located on centres of inversion. One of the two independent Mn atoms is seven-coordinate, binding to five carboxyl-ate O atoms from different chdc ligands and two phenanthrene N atoms from a dipyrido[3,2-a:2',3'-c]phenazine (L) ligand, while the second Mn atom is six-coordinate, binding to six carboxyl-ate O atoms from different chdc ligands. The cis-chdc ligands bridge the trinuclear Mn(II) clusters, forming chains, which are further linked into a three-dimensional network.

acta crystallographica. section e

Poly[di-μ-cis-cyclohexane-1,4-dicarboxylato-μ-trans-cyclohexane-1,4-dicarboxylato-bis[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)]