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The complex molecule of the title compound, [Mn 3 (C 7 H 5 O 2 ) 6 (C 10 H 8 N 2 ) 2 ]·H 2 O, contains a linear array of divalent manganese ions. The central Mn II  atom, which is located on a crystallographic inversion center, is coordinated octa­hedrally by six benzoate O atoms. The two terminal Mn II  ions are six-coordinated by four benzoate O atoms and two N atoms of 2,2′-bipyridyl. The central Mn II  atom and the terminal Mn II  ions are bridged by four benzoate ligands in a bidentate fashion, whereas the other two carboxyl­ate ligands form bridges through one O atom only and chelate the terminal Mn II  atom. The mol­ecules pack together  via  van der Waals attractions and C—H⋯O hydrogen bonds.

Hexa-μ2-benzoato-bis(2,2′-bipyridyl)trimanganese(II) monohydrate

Hexa-μ₂-benzoato-bis(2,2′-bipyridyl)trimanganese(II) monohydrate