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The title compound, [Mn(C 4 H 3 N 8 ) 2 (H 2 O) 4 ]·2H 2 O, represents the first structurally characterized transition metal complex of the 1,2-bis­(tetra­zol-5-yl)ethene ligand. The complex mol­ecule occupies a special position on an inversion centre and the Mn atom has a tetra­gonally distorted octa­hedral coordination. The bis­(tetra­zolyl)ethene ligand is planar within 0.0366 (7) Å. All ‘active’ H atoms participate in hydrogen bonds, which link mol­ecules of the complex and the uncoordinated water mol­ecules into an infinite three-dimensional framework.

Tetraaquabis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN2}manganese(II) dihydrate

Tetraaquabis{5-[2-(1H-tetrazol-5-yl)ethenyl]pyrazolato-κN²}manganese(II) dihydrate