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The title compound, [CuBr(C 9 H 9 N 5 )]  n  , prepared by the solvothermal treatment of CuBr with 4-(2-allyl-2 H -tetra­zol-5-yl)pyridine, is a new homometallic Cu I –olefin coordination polymer in which dinuclear Cu 2 Br 2  units are linked by the organic olefin ligand 4-(2-allyl-2 H -tetra­zol-5-yl)pyridine, which acts as a bidentate ligand connecting two neighbouring Cu 2 Br 2  units through the pyridine N atom and the double bond of the allyl group. The coordination of Cu(I) is slightly distorted tetrahedral.

catena-Poly[[di-μ-bromido-dicopper(I)]bis[μ-η2,σ1-4-(2-allyl-2H-tetrazol-5-yl)pyridine]]

catena-Poly[[di-μ-bromido-dicopper(I)]bis[μ-η²,σ¹-4-(2-allyl-2H-tetrazol-5-yl)pyridine]]