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The title compound, [Sr(C 14 H 20 O 5 ) 2 ](I 3 ) 2 , obtained by slow evaporation of an ethanol/dichloro­methane solution (1:1) of SrCl 2 , benzo-15-crown-5 and I 2 , is built of sandwich-like [Sr(benzo-15-crown-5) 2 ] 2+  cations and isolated linear I 3−  anions which are arranged in alternating layers parallel to (010). The triiodide anions are located in general positions, whereas the cations are located on centres of inversion.

Bis(benzo-15-crown-5-κ5O)strontium bis(triiodide)

Bis(benzo-15-crown-5-κ⁵O)strontium bis(triiodide)