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In the title complex, [Ni(NCS) 2 (C 14 H 13 N 3 ) 2 ]·2CH 3 OH, the Ni II  atom lies on a crystallographic twofold rotation axis and is in a slightly distorted octa­hedral NiN 6  coordination environment. The crystal structure is stabilized by a combination of weak π–π stacking inter­actions between symmetry-related 1,10-phenanthroline ligands [centroi–centroid distance between benzene rings = 3.5936 (18) Å] and weak O—H⋯S, C—H⋯O and C—H⋯S hydrogen bonds between methanol and complex mol­ecules.

Bis(2-dimethylamino-1,10-phenanthroline-κ2N,N′)bis(thiocyanato-κN)nickel(II) methanol disolvate

Bis(2-dimethylamino-1,10-phenanthroline-κ²N,N′)bis(thiocyanato-κN)nickel(II) methanol disolvate