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The mol-ecule of the title compound, [Zn(C(28)H(30)N(2)O(2))(CH(3)COCH(3))], lies across a mirror plane with the Zn(II) ion and the acetone mol-ecule on the mirror plane. The Zn(II) ion is in a five-coordinate distorted square-pyramidal N(2)O(3) environment, with the two imine N and two phenolic O atoms of the tetra-dentate Schiff base dianion in the basal plane and the acetone mol-ecule in the apical position. The central benzene ring makes a dihedral angle of 16.5 (2)° with the two outer phenolate rings. In the crystal structure, the mol-ecules are arranged into anti-parallel columns along the a axis.

acta crystallographica. section e

(Acetone-κO){6,6′-di-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}zinc(II)