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The title compound, [V(C(16)H(14)N(2)O(2))O], was synthesized by the reaction of vanadyl(IV) sulfate and N,N'-bis-(salicyl-idene)ethyl-enediamine under hydro-thermal conditions. The asymmetric unit contains two mol-ecules. Each V(IV) atom is coordinated in a square-pyramidal geometry by two N atoms and two O atoms from a ligand in the basal plane and by an oxide O atom in the apical position. Weak C-H⋯O hydrogen bonds lead to a three-dimensional supra-molecular structure.

{2,2′-[Ethylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}oxidovanadium(IV)

{2,2′-[Ethylenebis(nitrilomethylidyne)]diphenolato-κ⁴O,N,N′,O′}oxidovanadium(IV)