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The absolute configuration of the octa­hedral  fac -CoN 3 O 3  title complex, [Co(C 5 H 8 NO 2 ) 3 ]·3H 2 O, has been determined by single-crystal X-ray analysis. A three-dimensional network of hydrogen bonds is observed between the proline carboxyl­ate groups and the three uncoordinated water mol­ecules.

(−)545-fac-Δ-Tris(L-prolinato)cobalt(III) trihydrate

(−)₅₄₅-fac-Δ-Tris(L-prolinato)cobalt(III) trihydrate