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The title Cu I  coordination polymer, [Cu 2 Cl 2 (C 30 H 28 N 6 )]  n  , was obtained by reaction of CuCl 2 ·2H 2 O and 1,4-bis­[1-(3-pyridyl­meth­yl)-1 H -benzimidazol-2-yl]butane. Each Cu I  cation is three-coordinated by a ClN 2  donor set. The anion acts as a tetra­dentate ligand, linking Cu I  centres into a polymeric chain.

Poly[bis[chloridocopper(I)]-μ4-1,4-bis[1-(3-pyridylmethyl)-1H-benzimidazol-2-yl]butane]

Poly[bis[chloridocopper(I)]-μ₄-1,4-bis[1-(3-pyridylmethyl)-1H-benzimidazol-2-yl]butane]