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In the title complex, [Hg(2)I(4)(C(26)H(20)FOP)(2)], the Hg(II) centre is four-coordinate with one short Hg-I bond [2.6895 (7) Å], one Hg-C bond and two asymmetric bridging Hg-I bonds with distances of 2.7780 (8) and 3.2599 (8) Å. The title mol-ecule has a crystallographic inversion centre at the centroid of the four-membered ring formed by the two Hg atoms and two I atoms. The crystal packing is stabilized by C-H⋯O hydrogen bonds.

Di-μ-iodido-bis{[(4-fluorobenzoylmethylene)triphenyl-λ5-phosphorane]iodidomercury(II)}

Di-μ-iodido-bis{[(4-fluorobenzoylmethylene)triphenyl-λ⁵-phosphorane]iodidomercury(II)}