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Both imine bonds of the title compound, C 21 H 21 N 3 O 4 S 2 , were found to be in the  E  configuration. The terminal pyrrole and thio­phene rings are twisted by 2.5 (3) and 2.3 (2)°, respectively, from the mean plane of the central thio­phene to which they are attached. The structure is disordered by exchange of the terminal heterocyclic rings; the site occupancy factors are  ca  0.8 and 0.2. The crystal packing involves some π–π stacking [3.449 (4) Å between pyrrole and terminal thio­phene rings].

Diethyl 2-[(1-methyl-1H-pyrrol-2-yl)methyleneamino]-5-(2-thienylmethyleneamino)thiophene-3,4-dicarboxylate