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In the title fused-ring compound, C 12 H 13 NO 3 , the two five-membered C 3 NO rings both approximate to envelope conformations with C atoms in the flap positions. The OH group of the pendant CH 2 OH unit is disordered over two positions in a 0.528 (5):0.472 (5) ratio. One of the OH groups participates in an O—H⋯N hydrogen bond, generating centrosymmetric dimers in the crystal structure.

1-Hydroxymethyl-3,12-dioxa-14-azatetracyclo[9.2.1.04,14.05,10]tetradecane

1-Hydroxymethyl-3,12-dioxa-14-azatetracyclo[9.2.1.0^4,14.0^5,10]tetradecane