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In the title polymeric complex, [Cd(C 5 H 4 NO 3 S) 2 (H 2 O) 2 ]  n  , the Cd atom is located on a centre of inversion and is coordinated by two O atoms and two N atoms, derived from four different pyridine-3-sulfonate ligands, and two O atoms derived from two water mol­ecules, forming a distorted  trans -N 2 O 4  octa­hedral geometry. The topology of the polymer is a one-dimensional chain mediated by bridging pyridine-3-sulfonate anions. These are connected into a three-dimensional architecture  via  hydrogen bonds.

catena-Poly[[diaquacadmium(II)]bis(μ-pyridine-3-sulfonato)-κ2N:O;κ2O:N]

catena-Poly[[diaquacadmium(II)]bis(μ-pyridine-3-sulfonato)-κ²N:O;κ²O:N]