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In the title salt, C 23 H 26 N 42+ ·2C 6 H 2 N 3 O 7− , the dihedral angle between the imidazolium rings in the dication is 69.9 (1)°. The aromatic ring of the benzyl group is almost perpendicular to the  N -heterocyclic ring that is directly connected to it [dihedral angles = 83.2 (2) and 77.3 (3)°].

3,3′-Dibenzyl-2,2′-dimethyl-1,1′-methylenediimidazolium dipicrate