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Rochelle salt, K(+)·Na(+)·C(4)H(4)O(6) (2-)·4H(2)O, is known for its remarkable ferroelectric state between 255 and 297 K. The current investigation, based on data collected at 105 K, provides very accurate structural information for the low-temperature paraelectric form. Unlike the ferroelectric form, there is only one tartrate molecule in the asymmetric unit, and the structure displays no disorder to large anisotropic atomic displacements.

Potassium sodium (2R,3R)-tartrate tetrahydrate: the paraelectric phase of Rochelle salt at 105 K