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In the crystal structure of the title compound, C14H14F3O7P, the central chain, which connects the phosphate bicyclic system and the benzene ring, is made up of an approximately planar C&#8212;C(O)&#8212;O&#8212;C(H2) fragment and a C(H2)&#8212;O&#8212;C(Ph) link; the mean planes make a dihedral angle of 75.9&#8197;(2)&#176;. The F atoms are disordered over two positions; the site occupancy factors are ca 0.6 and 0.4

2-[3-(Trifluoromethyl)phenoxy]ethyl 1-oxo-2,6,7-trioxa-1λ5-phosphabicyclo[2.2.2]octane-4-carboxylate

2-[3-(Trifluoromethyl)phenoxy]ethyl 1-oxo-2,6,7-trioxa-1λ⁵-phosphabicyclo[2.2.2]octane-4-carboxylate