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The asymmetric unit of the title compound, [Mn(C 2 H 3 O 2 ) 2 (C 18 H 20 N 4 )]·6H 2 O, consists of a neutral Mn II  complex with six solvent water mol­ecules. In the complex, the Mn 2+  ion is eight-coordinated in a distorted square-anti­prismatic environment by four N atoms from the tetra­dentate ligand  N , N ′-bis­(2-pyridylmethyl­idene)cyclo­hexane-1,2-diamine (bpic) and four O atoms from two acetate ligands. The compound displays inter­molecular O—H⋯O hydrogen-bond inter­actions to form various kinds of ring structures and cyclic water clusters.

Diacetato[N,N′-bis(2-pyridylmethylidene)cyclohexane-1,2-diamine]manganese(II) hexahydrate