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The absolute configuration of the title complex, C 8 H 12 N + ·C 8 H 6 ClO 3−  or [ R -C 6 H 5 C(H)CH 3 NH 3 ][ S -4-ClC 6 H 4 C(H)(OH)CO 2 ], has been confirmed by the structure determination. In the crystal structure, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds form a two-dimensional network perpendicular to the  c  axis.

(R)-1-Phenylethanaminium (S)-4-chloromandelate