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The title compound, [ZnCl 2 (C 12 H 8 N 4 S)]  n  , was obtained by crystallization of 2,5-di-4-pyridyl-1,3,4-thia­diazole with ZnCl 2  in an MeOH/CHCl 3  solvent system. The structure contains infinite chains of ZnCl 2  units connected by the bifunctional thia­diazole ligands, with Zn II  adopting a distorted tetra­hedral coordination geometry. The dihedral angle between the two pyridyl rings in each ligand is 34.3 (1)°, and the dihedral angles between the thia­diazole ring and the two pyridyl rings are 18.3 (2) and 16.1 (2)°. The shortest Zn⋯Zn distance within each polymeric chain is 11.862 (3) Å, while the shortest inter­chain Zn⋯Zn distance is 7.057 (3) Å.

catena-Poly[[dichloridozinc(II)]-μ-2,5-di-4-pyridyl-1,3,4-thiadiazole-κ2N2:N5]

catena-Poly[[dichloridozinc(II)]-μ-2,5-di-4-pyridyl-1,3,4-thiadiazole-κ²N²:N⁵]