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The title complex, {[Cu 2 (C 10 H 8 N 2 )(C 25 H 22 P 2 ) 2 ](BF 4 ) 2 ·2.5CH 2 Cl 2 }  n  , contains chains of Cu I  centres bridged alternately by two (diphenyl­phosphino)methane (dppm) and 4,4′-bipyridine (bpy) ligands. Each Cu I  atom is coordinated by one N atom of 4,4′-bipyridine (bpy) and two P atoms of two (diphenyl­phosphino)methane (dppm) ligand, and has a trigonal-planar coordination geometry. There is an inversion centre midway between each pair of adjacent Cu atoms. The distance of two Cu I  atoms separated by two (diphenyl­phosphino)methane bridging ligands is 3.732 (3) Å, and 4,4′-bipyridine 11.138 (5) Å.

acta crystallographica. section e

catena-Poly[[copper(I)-bis[μ-bis(diphenylphosphino)methane-κ2P:P′]-copper(I)-μ-2,2′-bipyridine-κ2N:N′] bis(tetrafluoridoborate) dichloromethane 2.5-solvate]