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The title compound, C16H12N2O2S, was prepared by a Neigishi cross-coupling reaction to investigate the coordination chemistry of thiophene-containing ligands. In the molecule, the pyridine rings are twisted from the thiophene ring by 20.6&#8197;(1) and 4.1&#8197;(2)&#176;. The six-membered dihydrodioxine ring is in a half-chair conformation

5,7-Di-2-pyridyl-2,3-dihydrothieno[3,4-b][1,4]dioxine