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The title compound, [Ru(C 10 H 15 )(NO)(HOCH 2 CH 2 OH)](CF 3 SO 3 ) 2 , possesses a three-legged piano-stool geometry around the Ru atom, with an average Ru—O distance of 2.120 (6) Å and an Ru—N—O angle of 159.45 (14)°. The ethyl­eneglycol ligand forms a non-planar metallacyclic ring by chelating the Ru atom  via  the O atoms. The O⋯O distances of 2.554 (2) and 2.568 (2) Å are indicative of hydrogen bonding between coordinated ethyl­eneglycol and outer-sphere trifluoro­methane­sulfonate fragments. The crystal packing is stabilized by ionic forces and several CH 3 ⋯·F (2.585 and 2.640 Å) and CH 3 ⋯O inter­actions (2.391, 2.678, 2.694 and 2.699 Å) between the penta­methyl­cyclo­penta­dienyl ligand and trifluoro­methane­sulfonate anion. There is noticeable short inter­molecular contact [2.9039 (16) Å], between an O atom of the SO 3  group and a C atom of the penta­methyl­cyclo­penta­dienyl ligand.

(Glycol-κ2O,O′)nitrosyl(η5-pentamethylcyclopentadienyl)ruthenium(II) bis(trifluoromethanesulfonate)

(Glycol-κ²O,O′)nitrosyl(η⁵-pentamethylcyclopentadienyl)ruthenium(II) bis(trifluoromethanesulfonate)