English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The title compound, [Fe(2)Na(2)(C(23)H(14)ClN(3)O(3))(4)(C(2)H(3)N)(2)(H(2)O)(4)]·2H(2)O, is a hydrated Fe-azo complex dimer that is used as a charge-control agent in electrophotography. The mol-ecule is a centrosymmetric dimer with two octa-hedral Fe(III) units linked by two bridging five-coordinate Na(I) cations. Each Fe(III) atom is chelated by the N and two O atoms from two 3-anilinocarbonyl-1-[(5-chloro-2-oxidophen-yl)diazen-yl]-2-naph-tholate ligands. The Na(+) cation is coordinated by a carbonyl O atom from the two ligands of each octa-hedral Fe(III) unit, two water mol-ecules and the N atom of an acetonitrile mol-ecule. Two solvent water mol-ecules complete the structure. In the crystal structure, the dimeric mol-ecules are bridged by a pair of discrete inter-molecular O-H⋯O hydrogen bonds, one of which involves a sodium-bound water mol-ecule and a hydrate water, and the other a 5-chloro-phenolate O atom and a water molecule to form an extended chain along b.

Diacetonitriletetrakis{μ2-3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato}tetraaquadiiron(III)disodium(I) dihydrate

Diacetonitriletetrakis{μ₂-3-anilinocarbonyl-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato}tetraaquadiiron(III)disodium(I) dihydrate