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The title compound, [RuCl 2 (C 2 H 3 N) 2 (C 18 H 15 P) 2 ]·2C 2 H 3 N, was obtained upon stirring an acetonitrile/ethanol solution of [RuCl 2 (PPh 3 ) 3 ]. In the crystal structure, each Ru II  ion is coordinated by two Cl [Ru—Cl = 2.4308 (7) and 2.4139 (7) Å], two N [Ru—N = 2.016 (2) and 2.003 (2) Å], and two P [Ru—P = 2.3688 (7) and 2.3887 (7) Å] atoms in a distorted octa­hedral geometry. Packing inter­actions include typical C—H⋯π contacts involving phenyl groups as well as weak hydrogen bonds between CH 3 CN methyl H atoms and Cl or solvent CH 3 CN N atoms.

cis-cis-trans-Bis(acetonitrile-κN)dichloridobis(triphenylphosphine-κP)ruthenium(II) acetonitrile disolvate