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The title compound, C25H24O3, synthesized as a potential chiral catalyst, exhibits a range of C&#8212;C bond lengths in the pentacycloundecane cage between 1.5144&#8197;(18) and 1.5856&#8197;(16)&#8197;&#197;. The two benzene rings are not planar with respect to each other, but rather are twisted at a torsion angle of 34.67&#8197;(17)&#176;. The molecule has an intramolecular O&#8212;H...O interaction and participates in two C&#8212;H...O intermolecular interactions to form a one-dimensional chain

8-(Biphenyl-4-yl)-8-hydroxypentacyclo[5.4.0.02,6.03,10.05,9]undecan-11-one ethylene ketal

8-(Biphenyl-4-yl)-8-hydroxypentacyclo[5.4.0.0^2,6.0^3,10.0^5,9]undecan-11-one ethylene ketal