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The title compound, C26H22N4O2&#183;2CH3OH, was synthesized and characterized by 1H NMR spectroscopy and X-ray structure analysis. There is one half-molecule in the asymmetric unit with a centre of symmetry located at the centre of the benzene ring. The two bridged naphthyridine ring systems are in an antiparallel orientation. In the crystal structure, O&#8212;H...N, C&#8212;H...O and C&#8212;H...N interactions define the packing

7-[4-(5,7-Dimethyl-1,8-naphthyridin-2-yloxy)phenoxy]-2,4-dimethyl-1,8-naphthyridine methanol disolvate