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The central pyridine ring of the 2,2&#8242;:6&#8242;,2&#8242;&#8242;-terpyridine fragment of the title compound, C29H29N3O6, forms dihedral angles of 5.2&#8197;(5), 10.1&#8197;(5) and 86.0&#8197;(6)&#176;, respectively, with the two outer pyridine rings and the benzene ring of the benzo-15-crown-5 fragment

4′-(2,5,8,11,14-Pentaoxabicyclo[13.4.0]nonadeca-15,17,19-trien-17-yloxy)-2,2′:6′,2′′-terpyridine: a powder study