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In the title compound, {[Ag(C12H11N3O)]NO3&#183;H2O}n, the Ag atom is coordinated by two N atoms from the heterocyclic ligand, giving a linear polycationic chain. Two long Ag...Onitrate interactions [2.667&#8197;(3) and 2.840&#8197;(3)&#8197;&#197;] result in a three-dimensional network. The water molecule consolidates the network structure by forming hydrogen bonds, one to the polycationic chain and one to the nitrate anion

catena-Poly[[silver(I)-μ-N-(3-pyridylmethyl)pyridine-4-carboxamide] nitrate monohydrate]