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In the title molecule, C18H20N2O4, which resides on a crystallographic centre of inversion (at the centre of the N&#8212;N bond), all non-H atoms apart from the methoxy substituent are approximately coplanar. The structure displays intramolecular O&#8212;H...N hydrogen bonding

1-(2-Hydroxy-5-methoxyphenyl)ethan-1-oneN-[(E)-1-(2-hydroxy-5-methoxyphenyl)ethylidene]hydrazone