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The title compound, C14H17NO2S2, was synthesized by asymmetric aldol condensation of N-acylthiazolidinethione with acetaldehyde. In the molecule, the thiazolidine five-membered ring assumes an envelope conformation. Intermolecular C&#8212;H...O and intramolecular O&#8212;H...O and C&#8212;H...S hydrogen bonding helps to stabilize the structure

(S)-1-[(S)-4-Benzyl-2-thioxothiazolidin-3-yl]-3-hydroxybutan-1-one